Product ID:Z*SPAR LINEAR POLYURETHANE COMP A & B (SUPP
MSDS Date:04/01/1990
FSC:8010
NIIN:00N016225
MSDS Number: BRRRN

KOP-COAT INC

436 7TH AVENUE
PITTSBURGH, PA 15219-1818
US

Emergency Phone: 800-553-5631, CHEMTREC 800-424-9300

Info Phone: 800-556-7737, 412-227-2155

Cage: 00297

KOP-COAT INC

PITTSBURGH, PA 15219-1818 US

Telephone: 800-553-5631, CHEMTREC 800-424-9300

Cage: 00297

BREATH OR ASTHMATIC ATTACK.

RTECS: 9999999ZZ

THIS MATL. PERSONS W/PRE-EXISTING NONSPECIFIC

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SYMPTOMS OF AN ASTHMA ATTACK.

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ACTIVATED CHARCOAL IN WATER TO VICTIM AS

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THERE IS NO

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TREATMENT SHOULD BE DIRECTED AT THE CONTROL OF

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REPORTED TO THE NRC (800-424-8802). WHEN PROD IS

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KEEP CONTRS CLSD WHEN MATL IS NOT IN USE.

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USE PRESS TO EMPTY DRUMS. DO NOT WEAR CONTAMD CLTHG.

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FLAME. EMPTY CONTRS MAY RETAIN PROD RESIDUE INCL

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OR NEAR FULL, PARTIALLY FULL OR EMPTY CONTRS. DO NOT

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OV FILTER UNITS O.K.

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BELOW FLAMM VAPOR CONC. LOCAL EXHST IS NEC FOR USE IN

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NIOSH PUBLICATION 87-113 "..... CONFINED SPACES".

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NECK COVER, APRONS, JACKETS, PANTS,

RTECS: 9999999ZZ

ACETIC ACID, ETHYL ESTER; (ETHYL ACETATE) (SARA III)

CAS: 141-78-6

RTECS: AH5425000

Fraction By Weight: 15-20%

OSHA PEL 400 PPM

ACGIH TLV: 400 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

XYLENE (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 1-5%

OSHA PEL 100 PPM; 150 STEL

ACGIH TLV: 100 PPM; 150 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ACETIC ACID, BUTYL ESTER; (N-BUTYL ACETATE)

CAS: 123-86-4

RTECS: AF7350000

Fraction By Weight: 1-5%

OSHA PEL 150 PPM;200 PPM STEL

ACGIH TLV: 150 PPM;200 PPM STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

HOMOPOLYMER OF HEXAMETHYLENE DIISOCYANATE (HDI)

CAS: 28182-81-2

RTECS: NQ9170000

Fraction By Weight: 15-20%

TITANIUM OXIDE; (TITANIUM DIOXIDE)

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 15-20%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST; 9293

565 G/L

RTECS: 9999999VO

ISOCYANATE EXPOS MAY LEAD TO RESP TRACT

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TRACT (MOUTH/THROAT/STOM/DIGESTIVE TRACT).

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SENSITIZED INDIV, UPON SUBSEQUENT EXPOS TO

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OR DELAYED (4-8 HRS AFTER EXPOS) RXN CONSISTING OF

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LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES:CONT OF LIQ/VAP MAY CAUSE SEV
IRRIT, TEARING, REDDENING & SWELLING. SKIN:RPTD/PRLNGD CONT MAY
CAUSE REDDENING, BLISTERING & IN SOME INDIV SKIN SENSIT RSLTG IN
DERM. ISOCYANATES CAN REACT W/SKIN P ROTEIN & MOISTURE RSLTG IN
IRRIT & DISCOLORATION. INHAL:INHAL OF HIGH CONC OF VAPS MAY CAUSE
CNS EFTS (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:CHARACT BY HDCH, DIZZ, WEAK, NAUS,
INCOORD & POSS COLLAPSE. INHAL OF HIGH CONC OF VAPS/MISTS CAN CAUSE
RESP TRACT IRRIT CUSING POSS BURNING SENSATION, RUNNY NOSE, SORE
THROAT, COUGHING, CHEST DISCOMFORT, SHORTNESS OF BREATH & REDUCED
LUNG FUNCTION. BRONCH, BRONCHIAL SPASM & PULM EDEMA MAY ALSO OCCUR.
(ING 7)
Medical Cond Aggravated by Exposure:INDIV W/PRE-EXISTING DISEASE IN, OR
A HISTORY OF AILMENTS INVOLVING SKIN, EYES, RESP TRACT, LIVER,
KIDNEYS & CNS ARE AT A GREATER THAN NORM RISK OF DEVELOPING ADVERSE
EFTS WHEN EXPOSED TO (ING 12)

First Aid:EYES:IMMED FLUSH W/LGE AMTS OF WATER FOR AT LEAST 15 MINS.
SEEK MED AID. SKIN:WASH THORO W/SOAP & WATER. IF
REDNESS/ITCHING/BURNING/OTHER SYMPS DEVELOP/PERSIST, SEEK MED AID.
WASH CONTAMD CLTHG BEFORE REUSE. INHAL:REMOVE FROM EXPOS. IF BRTHG
HAS STOPPED/IS DFCLT, ADMIN ARTF RESP/OXYGEN AS INDICATED. SEEK MED
AID. INGEST:DO NOT INDUCE VOM. GIVE 1 GLASS OF MILK OR 1-2 OZS
(30-60G) OF (ING 14)

Flash Point Method:TCC
Flash Point:50.0F,10.0C
Extinguishing Media:USE CARBON DIOXIDE, DRY CHEM OR FOAM. WATER MAY BE
INEFT. USE CARBON DIOXIDE, DRY CHEM, WATER SPRAY, ALCOHOL (SUP DAT)
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. USE WATER TO COOL FIRE-EXPOSED CONTR, STRUCTURE & TO PROT PERS.
Unusual Fire/Explosion Hazard:HEAT/FIRE CNDTNS:VAPS FROM FLAMM EXPLOS
MIX IN AIR. VAPS HEAVY, MAY TRAVEL (GROUND/PIT/SEWER) TO IGNIT
SOURCE & FLASH. OPEN/CLSD CONTRS MAY CONTAIN (SUP DAT)

Spill Release Procedures:STOP SPILL/LEAK IF NO RISK INVOLVED. AVOID
BRTHG VAPS. ELIM ALL SOURCES OF IGNIT. VENT AREA. AVOID CONT W/HOT
LIQ/FUMES. TAKE UP CAREFULLY TO AVOID HEAT/SPARKS. USE AN INERT
ABSORB TO COMPLETE CLEAN-U P. PROD RELSD INTO ENVIRON MUST BE
(ING17)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVOID PRLNGD/RPTD CONT W/SKIN OR EYES.
AVOID PRLNGD/RPTD BRTHG OF VAPS/MISTS/FUMES. SPRAY PAINT I/A/W OSHA
29CFR1910.107. PROT FROM PHYSICAL DAM.
Other Precautions:HANDLE/USE I/A/W OSHA 29CFR1910.106/LOC CODES.
OBSERVE GOOD PERSONAL HYGIENE PRACT & RECOM PROCS. STORE IN
AREAS/BLDGS DESIGNED TO COMPLY W/OSHA 1910.106. KEEP IN CLSD,
LABELED CONTR W/IN A COOL (WELL -SHADED), DRY, VENTD AREA. (ING 18)

Respiratory Protection:IF VENT DOES NOT MAINTAIN INHAL EXPOS BELOW
TLV(PEL), USE NIOSH/MSHA APPRVD UNITS AS PER CURRENT 29CFR1910.134
INSTRUCTION/WARNINGS & NIOSH-RESP DECISION LOGIC PUB #87-108. IF
W/IN OSHA PROT FACTOR, N IOSH/MSHA APPRVD AIR PURIFYING (ING 22)
Ventilation:PROVIDE SUFFICIENT GEN/LOC EXHST VENT IN PATTERN/VOL TO
CONTROL INHAL EXPOS BELOW CURRENT EXPOS LIMITS & AREAS (ING 23)
Protective Gloves:HEAVY DUTY NEOPRENE OR EQUAL GLOVES.
Eye Protection:CHEM WORK GOGGS &/FULL LNGTH FSHLD
Other Protective Equipment:WEAR INDUS-TYPE WORK CLTHG & SFTY FOOTWEAR.
DEPENDING ON WORK CNDTNS, WEAR RESIST PROT GARMENTS SUCH AS
HEAD/(ING 25)
Work Hygienic Practices:WASH EXPOSED AREAS PROMPTLY & THORO AFTER SKIN
CONT & BEFORE EATING/DRINKING/USING TOBACCO PRODUCTS OR REST ROOMS.
Supplemental Safety and Health
MFRS TRADE NAME/PART NO:(LP-100 WHITE), 6078621071001960. EXTING
MEDIA:OR UNIVERSAL TYPE FOAMS AS PER MFR'S RECOMMENDATIONS. EXPLO
HAZ:FLAMM/EXPLOS VAPS. CLSD CONTRS MAY EXPLODE WHEN EXPOSED TO
EXTREM E HEAT(FIRE). UNDER FIRE CNDTNS, MAY EMIT IRRIT/TOX GAS &/OR
FUMES.

HCC:F3
Vapor Density:>1
Spec Gravity:10-11
Solubility in Water:NEGLIGIBLE
Appearance and Odor:WHITE VISCOUS LIQUID W/A TYPICAL SOLVENT ODOR.
Percent Volatiles by Volume:45.5

Stability Indicator/Materials to Avoid:YES
AVOID OXIDIZING AGENTS.
Stability Condition to Avoid:AVOID HEAT, SPARKS & OPEN FLAMES.
Hazardous Decomposition Products:CARBON MONOXIDE & CARBON DIOXIDE UPON
THERMAL DECOMPOSITION.

Waste Disposal Methods:THIS PRODUCT IS A U.S. EPA DEFINED IGNITABLE
HAZARDOUS WASTE. DISPOSE OF AS AN IGNITABLE HAZARDOUS WASTE IN
ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.